Dana Vander Houwen, a spokeswoman for the Seattle Fire Department, said the unknown liquid was discovered on the first floor of the 911 call center at Ninth Avenue and Virginia Street.
Six to eight operators experienced some minor symptoms, including watery eyes, she said. Firefighters evacuated them as a precaution and are investigating the liquid.
Virginia is closed between Eighth and Ninth avenues, and Eighth is closed between Virginia and Stewart streets. And Ninth is closed between Virginia and Lenora.
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